The actress was pictured with her two sons Knox and Shiloh, looking low key wearing dark sunglasses.
The 42-year-old was dressed down in all-black attire as her entourage unloaded a car full of luggage.
Angelina’s arrival to the UK has sparked rumours she could be a guest at the St George’s Chapel, Windsor Castle on Saturday.
Express.co.uk has contacted a representative for Angelina Jolie.
Kensington Palace declined to comment.
Other celebrities rumoured to be joining Prince Harry and Meghan Markle on their big day are George and Amal Clooney, Ellie Goulding and Serena Williams.
Today, reports emerged that just three of the Spice Girls will be attending the wedding, ruling out any hopes of the group performing.
Page Six reported Emma Bunton, Geri Horner and Victoria Beckham have been invited, but Mel B and Mel C haven’t.
The news came after Mel B claimed the group were all attending the wedding, and hinted they could be performing.
Speaking on US Talk show The Real back in February, she said: “Yeah, I’m going… I don’t know if I should’ve said that!”
When pushed further by the panellists for more information, she added: “Well us five Spice Girls… why am I so honest?”
And when asked if they were to reunite and sing together, she revealed: “This is where I’m just like… I need to go. I’m going to be fired!”